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Rubrene (CAS 517-51-1) – High-Purity OLED/OFET Grade

  • Time of issue:Oct . 20, 2025 15:40
Tangshan Moneide Trading Co., Ltd. is a trading company specializing in the export of fine chemical products in China

(Summary description)Tangshan Moneide Trading Co., Ltd. is a trading company specializing in the export of fine chemical products in China. Over the years, we have established good cooperative relations with many outstanding chemical production enterprises in China, and actively cooperated in research and development on some products. Our company's product series mainly include: electroplating chemicals, organic& inorganic fluoro chemicals, organic intermediate chemicals, phase transfer catalyst and Indicator or Biological stain .

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Rubrene for next‑gen optoelectronics: what labs and fabs are really buying

If you work in OLEDs, OFETs, or photon upconversion, you’ve almost certainly handled rubrene at some point—probably with a mix of excitement and caution. It’s a classic organic semiconductor, fluorescent, stubbornly crystalline, and—when purified right—capable of wildly impressive charge mobility. I’ve seen teams move from “good enough” grades to high-purity material and unlock order-of-magnitude jumps in repeatability. That’s not hype; it’s process control.

Rubrene (CAS 517-51-1) – High-Purity OLED/OFET Grade

What it is (and why it still matters)

rubrene (Synonyms: 5,6,11,12‑Tetraphenylnaphthacene; CAS 517‑51‑1) remains a benchmark p‑type organic semiconductor. In single crystals, mobility can reach the teens (cm²/V·s), which is still jaw‑dropping. In thin films, you won’t hit those numbers, but you’ll get reliable hole transport and a bright yellow‑orange emission band—handy for OLED dopants, scintillation, and triplet–triplet annihilation upconversion (TTA‑UC).

Industry trends I’m seeing

  • Shift to tighter spec windows: HPLC ≥99.5% and metal ppm controls for device stability.
  • More gradient-sublimed lots for pilot lines; batch-to-batch certificates are now table stakes.
  • Growing demand for TTA‑UC in sensors and niche photovoltaics; OLED dopant use is steady.

Product specs (typical, real-world use may vary)

Chemical name 5,6,11,12‑Tetraphenylnaphthacene (rubrene)
CAS No. 517‑51‑1
Purity (HPLC) ≥99.5% (typical lots 99.7% ≈)
Melting point ≈329–331 °C
PL peak (solution) ≈560–570 nm; thin‑film red‑shift possible
Residual metals
QC methods HPLC, NMR, MS, TGA (ASTM E1131), DSC, UV‑Vis, XRD

Where it’s used

  • OLED dopant (yellow emitter) and host blending experiments.
  • OFET channel layers; single‑crystal mobility benchmarks.
  • TTA‑UC systems with Pd‑/Pt‑porphyrin sensitizers for low‑light sensing.
  • Scintillator research and organic lasers—niche but interesting.

Process flow you can actually replicate

  1. Materials: technical‑grade rubrene feedstock; high‑purity nitrogen/argon; quartz boats.
  2. Methods: multi‑step gradient sublimation under high vacuum; optional zone‑refining for R&D crystals.
  3. Testing: HPLC area %; ICP‑MS for metals; TGA/DSC; PL/absorption mapping; XRD for crystallinity.
  4. Standards: ISO 9001 QC framework; ISO/IEC 17025 lab methods; ASTM E1131 for TGA; IEC 62341 guidance for OLED device testing environments.
  5. Packaging: amber glass, inert back‑fill, moisture/oxygen barrier pouch.
  6. Service life: 24 months sealed at 2–8 °C, dark, inert; open handling in N2 glovebox recommended.
  7. Industries: display R&D, wearables, sensors, academic materials science, photonics startups.

Vendor comparison (indicative)

Vendor Purity QC docs Lead time Customization
Moneidechem (Hebei, China) ≥99.5% HPLC COA + HPLC + ICP‑MS 7–12 days ≈ Lot size, metal‑ppm targeting
Supplier B (global) ≥98–99% COA 10–20 days Limited
Supplier C (R&D focus) ≥99% COA + NMR Stock dependent Small‑batch only

Customization and feedback

Teams often request tighter ICP‑MS thresholds for rubrene (e.g., Fe, Cu, Ni

Origin and logistics: 2‑7‑523 Jidong Building Materials, Tangshan, Hebei 064000, China. Export documentation usually includes COA, MSDS, and REACH/RoHS declarations.

Quick case notes

  • OFET group improved mobility from ~0.7 to 1.4 cm²/V·s in thin films after switching to gradient‑sublimed rubrene and oxygen‑scrubbed solvents.
  • TTA‑UC team reported 15–20% stronger UC emission at the same pump power with low‑ppm‑metal lots (same device stack).

Safety and handling

Handle rubrene in a dry N2 environment; minimize light/oxygen exposure. Follow standard PPE. Dispose according to local regulations; consult MSDS.

References

  1. Podzorov, V. et al. High-mobility field-effect transistors based on single-crystal rubrene. Applied Physics Letters 82, 1739–1741 (2003).
  2. Cheng, Y.-Y. et al. Solid-state visible-to-UV photon upconversion via TTA using rubrene. The Journal of Physical Chemistry Letters 1, 1795–1799 (2010).
  3. ASTM E1131-20: Standard Test Method for Compositional Analysis by Thermogravimetry.
  4. IEC 62341: Organic light emitting diode (OLED) displays – Performance requirements.
  5. ISO/IEC 17025: General requirements for the competence of testing and calibration laboratories.

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