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Sodium diethyldithiocarbamate trihydrate

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1000
同义词:
 
CAS 编号:
20624-25-3
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关键词:
描述
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化学名称

Sodium diethyldithiocarbamate trihydrate

同义词

Diethyldithiocarbamic acid sodium salt trihydrate

CAS 编号

20624-25-3

分子式

C5H10NNaS2·3H2O

EINECS 编号

205-710-6

分子量

225.31

分子结构

细节

Appearance: White crystal

Assay: 99.0%min

Melting point: 94-96℃

Solubility in water: Passes test

Sulfated ash (SO42-): 30.5—32.5%

Sensitivity as reagent for Copper: Passes test

Solubility: Solve in water, water liquor instability;

solve in alcohol insolve in aether and chloroform.

 

主要应用

Copper chromogenic reaction, the colorimetric

determination heavy metal extracting a few such as

copper, cadmium, vanadium, nickel and cobalt.

As good of collector of copper, lead, antimony sulfide

ore ,also can make rubber vulcanization promoting agents.

 

What is sodium diethyldithiocarbamate used for?


Sodium diethyldithiocarbamate (NaDDC) serves as a versatile chelating agent with applications spanning analytical chemistry, industrial processes, and rubber manufacturing. In analytical laboratories, it's primarily used for the quantitative precipitation and spectrophotometric determination of copper and other transition metals. The compound functions as an accelerator in rubber vulcanization processes, significantly improving cross-linking efficiency. Environmental applications include heavy metal removal from wastewater through selective chelation. In biochemistry, it acts as an inhibitor for certain metalloenzymes. The pharmaceutical industry employs it as an intermediate in drug synthesis, while agricultural applications utilize its fungicidal properties. Its ability to form stable complexes with numerous metal ions makes it particularly valuable for metal ion separation and recovery operations.

 

What is sodium diethyldithiocarbamate?


Sodium diethyldithiocarbamate is an organosulfur compound with the chemical formula (C₂H₅)₂NCS₂Na, representing the sodium salt of diethyldithiocarbamic acid. This white to off-white crystalline powder exhibits good water solubility and characteristic sulfurous odor. The molecule features a central nitrogen atom bonded to two ethyl groups and a dithiocarbamate functional group (-CS₂⁻), which provides exceptional metal-chelating capabilities. As a dialkyldithiocarbamate derivative, it belongs to an important class of sulfur-containing compounds with diverse chemical reactivity. The compound's stability in aqueous solution and rapid complexation kinetics make it particularly useful for both industrial and laboratory applications requiring immediate metal ion sequestration.

 

What is the feature of sodium diethyldithiocarbamate?

 

Sodium diethyldithiocarbamate's most distinctive feature is its exceptional metal-chelating capacity, forming stable, water-insoluble complexes with numerous transition metals. The compound exhibits rapid reaction kinetics, enabling immediate complexation upon contact with metal ions. Its water solubility allows for easy application in aqueous systems, while the resulting metal complexes typically precipitate completely. The dithiocarbamate functional group provides excellent nucleophilic character, participating in various organic transformations. Thermal stability up to 100°C makes it suitable for industrial processes, though it decomposes at higher temperatures. The compound's reducing properties and radical scavenging ability contribute to its effectiveness in rubber vulcanization and antioxidant applications. These combined characteristics make it uniquely valuable across multiple scientific and industrial disciplines.

 

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