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High Purity Tetraethyl Ammonium Tetrafluoroborate - Electrolyte

  • Время выпуска:Авг . 31, 2025 06:20
Tangshan Moneide Trading Co., Ltd. — торговая компания, специализирующаяся на экспорте продукции тонкого химического синтеза в Китае.

(Краткое описание)Tangshan Moneide Trading Co., Ltd. — торговая компания, специализирующаяся на экспорте чистых химических продуктов в Китае. За эти годы мы установили хорошие отношения сотрудничества со многими выдающимися предприятиями по производству химических продуктов в Китае и активно сотрудничали в исследованиях и разработках некоторых продуктов. Серия продуктов нашей компании в основном включает: гальванические химикаты, органические и неорганические фторсодержащие химикаты, органические промежуточные химикаты, катализаторы фазового переноса и индикаторные или биологические красители.

Информация

Introduction to Tetraethyl Ammonium Tetrafluoroborate

In the rapidly evolving landscape of advanced materials and electrochemical systems, tetraethyl ammonium tetrafluoroborate stands out as a critically important chemical compound. Also known by its CAS number 429-06-1 and sometimes referred to as tetra ethyl ammonium tetrafluoroborate, this quaternary ammonium salt is highly valued for its unique ionic properties and broad applicability. It functions primarily as an electrolyte component, offering high ionic conductivity and a wide electrochemical window, which are indispensable characteristics for high-performance energy storage devices and advanced chemical synthesis.

The chemical, with its precise molecular structure, is a cornerstone in the development of cutting-edge technologies. Its exceptional thermal stability and solubility in various organic solvents make it a versatile choice for applications demanding rigorous performance under diverse operating conditions. Manufacturers and researchers continually seek high-purity grades of this compound to ensure the reliability and efficiency of their end products, ranging from next-generation batteries and supercapacitors to sophisticated catalytic systems.

Manufacturing Process Flow of Tetraethyl Ammonium Tetrafluoroborate

The production of high-purity tetraethyl ammonium tetrafluoroborate (TEABF₄) involves a sophisticated multi-stage chemical synthesis and purification process, ensuring the final product meets stringent industrial requirements. The primary raw materials typically include tetraethylammonium bromide or iodide, and a source of tetrafluoroborate, such as sodium tetrafluoroborate or fluoroboric acid.

Schematic Process Steps:

  1. 1. Raw Material Preparation: High-grade tetraethylammonium halide (e.g., (C₂H₅)₄NBr) and an appropriate tetrafluoroborate source (e.g., NaBF₄ or HBF₄) are sourced and pre-treated to ensure purity. Solvents, typically organic, are also prepared.
  2. 2. Reaction (Metathesis): In a controlled reactor, the tetraethylammonium halide is reacted with the tetrafluoroborate source. For instance, if using NaBF₄, a double displacement reaction occurs:
    (C₂H₅)₄NBr + NaBF₄ → (C₂H₅)₄NBF₄ + NaBr
    This reaction is typically conducted in a suitable solvent at specific temperatures and pressures to optimize yield and selectivity.
  3. 3. Filtration: Following the reaction, insoluble byproducts (e.g., NaBr, if used) are removed through filtration. This step is critical for minimizing impurities and enhancing the purity of the crude product.
  4. 4. Recrystallization/Purification: The crude tetraethyl ammonium tetrafluoroborate is then subjected to one or more recrystallization steps using appropriate solvent systems. This is the primary method for achieving the high purity levels required for electrochemical applications, often reaching >99.0% or even >99.9%. Other purification techniques like activated carbon treatment may also be employed.
  5. 5. Drying: The purified product is meticulously dried under vacuum at controlled temperatures to remove residual solvents and moisture. Extreme care is taken to prevent reabsorption of moisture, which can compromise the product's electrochemical performance.
  6. 6. Quality Control & Packaging: The final dried product undergoes rigorous quality control testing (e.g., assay, moisture content, ion chromatography for halide impurities, NMR spectroscopy) to ensure it meets specified technical standards, such as those derived from ISO 9001 guidelines for chemical manufacturing. It is then packaged in inert atmosphere to maintain its integrity and stability.

Manufacturing processes are continuously refined to improve energy efficiency and reduce waste, aligning with modern sustainability goals. The careful control of each stage ensures excellent product quality, contributing to enhanced service life and performance in target industries like energy storage (supercapacitors, lithium-ion batteries), electrochemistry, and specialized organic synthesis. The advantages demonstrated in typical application scenarios include superior stability under electrochemical cycling, leading to longer device lifespan, and high purity which minimizes undesirable side reactions.

High Purity Tetraethyl Ammonium Tetrafluoroborate - Electrolyte

Industry Trends and Market Insights

The market for tetraethyl ammonium tetrafluoroborate is experiencing robust growth, driven by escalating demand in high-tech sectors. A significant trend is the relentless pursuit of more efficient and sustainable energy storage solutions. Supercapacitors, for instance, are increasingly critical for applications requiring rapid charge/discharge cycles and high power density, such as electric vehicles (EVs), renewable energy systems, and consumer electronics. The role of TEABF₄ as a key electrolyte component in these devices positions it at the forefront of this market expansion.

Another major driver is the advent of next-generation battery technologies. While traditional lithium-ion batteries dominate, research into alternative chemistries and enhanced electrolyte formulations heavily relies on compounds like tetraethyl ammonium tetrafluoroborate to push performance boundaries. The push for safer, more stable, and higher-energy-density batteries fuels innovation and increases the demand for high-purity electrochemical-grade materials. Furthermore, the burgeoning field of ionic liquids and their applications in various chemical processes, from catalysis to solvent systems, also contributes to the compound's market trajectory. The global focus on decarbonization and electrification ensures a sustained upward trend for specialized chemicals essential to these technologies.

Technical Specifications and Properties

Тетрафторборат тетраэтиламмония (CAS No. 429-06-1) possesses a unique set of physicochemical properties that make it indispensable for demanding electrochemical and synthetic applications. Its high ionic conductivity, wide electrochemical window, and excellent thermal stability are key attributes.

Typical Product Specifications for Tetraethyl Ammonium Tetrafluoroborate
Parameter Specification Test Method
Chemical Name Tetraethyl Ammonium Tetrafluoroborate N/A
CAS Number 429-06-1 N/A
Molecular Formula (C₂H₅)₄NBF₄ N/A
Molecular Weight 217.06 g/mol N/A
Purity ≥ 99.0% (Electrochemical Grade) Titration / HPLC
Water Content ≤ 20 ppm Karl Fischer Titration
Halide Content (Cl-, Br-) ≤ 10 ppm Ion Chromatography (IC)
Появление White Crystalline Powder Visual Inspection
Melting Point ~275-280 °C (Dec.) DSC
Solubility Soluble in common organic solvents (e.g., Acetonitrile, Propylene Carbonate) N/A
Electrochemical Window ~4.5 V (vs. Ag/Ag+) in Acetonitrile Cyclic Voltammetry
High Purity Tetraethyl Ammonium Tetrafluoroborate - Electrolyte

Application Scenarios

The versatility of tetraethyl ammonium tetrafluoroborate allows its integration into a wide array of advanced technological applications, particularly where high performance, stability, and efficiency are paramount.

  • Electrolyte for Supercapacitors (EDLCs): This is arguably the most prominent application. Тетрафторборат тетраэтиламмония is a key component in the electrolyte formulations for electrical double-layer capacitors (EDLCs). Its excellent ionic conductivity and wide electrochemical window enable high power density and extended cycle life for supercapacitors used in hybrid electric vehicles, industrial power backup, and consumer electronics. The compound ensures stable performance over thousands of charge-discharge cycles, significantly outperforming many traditional battery systems in terms of durability.
  • Electrolyte for Lithium-ion and Redox Flow Batteries: Beyond supercapacitors, it finds use in advanced battery research, especially in non-aqueous lithium-ion battery electrolytes and certain types of redox flow batteries. Its stability helps to mitigate electrolyte decomposition, enhancing the safety and longevity of battery systems.
  • Phase-Transfer Catalysis: In organic synthesis, tetraethyl ammonium tetrafluoroborate can act as a phase-transfer catalyst, facilitating reactions between reactants in immiscible phases. Its ability to transport ions across phase boundaries improves reaction rates and yields, reducing the need for harsh conditions or expensive solvents, thereby offering energy-saving benefits.
  • Precursor for Ionic Liquids: It serves as a valuable precursor in the synthesis of more complex ionic liquids. The tetraethylammonium cation and tetrafluoroborate anion are stable building blocks for creating tailored ionic liquid systems with specific properties for solvent, catalytic, or electrochemical applications.
  • Electroplating and Surface Treatment: In certain specialized electroplating baths, it can contribute to enhanced conductivity and improved deposition characteristics, leading to superior corrosion resistance and surface finish for metallic components.

These diverse applications underscore the critical role of high-purity tetraethyl ammonium tetrafluoroborate in driving innovation across various B2B sectors, from automotive and electronics to specialized chemical manufacturing.

High Purity Tetraethyl Ammonium Tetrafluoroborate - Electrolyte

Technical Advantages of Tetraethyl Ammonium Tetrafluoroborate

The selection of tetraethyl ammonium tetrafluoroborate over alternative electrolyte salts or catalytic agents is often predicated on its significant technical advantages:

  • Exceptional Ionic Conductivity: The relatively small and symmetrical nature of the tetraethylammonium cation, combined with the stable tetrafluoroborate anion, results in high mobility in various organic solvents. This translates directly to high power density and efficient energy transfer in electrochemical devices, crucial for applications like supercapacitors.
  • Wide Electrochemical Window: Тетрафторборат тетраэтиламмония exhibits a broad range of electrochemical stability, typically exceeding 4.5 V in common organic solvents. This allows for higher operating voltages in energy storage devices, leading to increased energy density and improved overall performance without electrolyte decomposition.
  • High Thermal Stability: The compound is thermally stable up to approximately 270-280 °C (with decomposition), making it suitable for applications that may experience elevated temperatures. This stability contributes to the long-term reliability and safety of devices.
  • Excellent Solubility: It demonstrates good solubility in a range of polar aprotic solvents commonly used in electrochemistry, such as acetonitrile (AN), propylene carbonate (PC), and γ-butyrolactone (GBL). This solubility facilitates the formulation of diverse electrolyte solutions tailored to specific device requirements.
  • Low Moisture and Halide Content (High Purity Grades): For electrochemical applications, even trace amounts of water or halide ions can severely degrade performance and device longevity. High-grade tetraethyl ammonium tetrafluoroborate is produced with ultra-low moisture and halide content, ensuring superior electrochemical stability and minimal parasitic reactions.
  • Corrosion Resistance and Device Longevity: The chemical inertness of the tetrafluoroborate anion contributes to reduced corrosion of device components and electrodes, thereby extending the service life of supercapacitors and batteries.

These intrinsic advantages underscore why tetraethyl ammonium tetrafluoroborate remains a preferred choice for engineers and researchers developing high-performance electrochemical systems and advanced chemical processes.

Vendor Comparison: Ensuring Quality and Reliability

Choosing the right supplier for tetraethyl ammonium tetrafluoroborate is crucial for B2B clients, as product quality directly impacts the performance and reliability of their end applications. Vendors differentiate themselves not only on price but significantly on purity, consistency of supply, technical support, and adherence to quality standards.

Comparative Analysis of Tetraethyl Ammonium Tetrafluoroborate Vendors (Illustrative)
Feature/Vendor MoneideChem (Example) Vendor B Vendor C
Purity (Electrochemical Grade) ≥99.0% to >99.9% ≥98.5% ≥99.5%
Moisture Content ≤20 ppm ≤50 ppm ≤15 ppm
Halide Ions (Cl-, Br-) ≤10 ppm ≤30 ppm ≤5 ppm
Manufacturing Standards ISO 9001, REACH compliant Internal QC ISO 9001
Packaging Options Customizable (50g to kg) in inert atmosphere Standard (100g, 1kg) Bulk (5kg+)
Technical Support Dedicated R&D, application engineers Basic customer service Limited technical advice
Lead Time (Typical) 1-2 weeks 2-4 weeks 2-3 weeks

MoneideChem, for example, emphasizes stringent quality control, offering high-purity grades that meet the demanding specifications of electrochemical research and industrial applications. This commitment extends to thorough impurity analysis, including ultra-low moisture and halide content, which are critical for preventing degradation and ensuring long-term stability in sensitive devices. Partnering with a reliable vendor like MoneideChem guarantees not only product excellence but also robust technical support and a responsive supply chain, essential for maintaining continuous production and accelerating R&D cycles.

High Purity Tetraethyl Ammonium Tetrafluoroborate - Electrolyte

Customized Solutions for Specific Applications

Recognizing that every industrial application has unique requirements, specialized suppliers offer customized solutions for tetraethyl ammonium tetrafluoroborate. This flexibility is vital for clients operating at the cutting edge of material science and electrochemical engineering. Customization can involve several aspects:

  • Tailored Purity Levels: While electrochemical grade (≥99.0%) is standard, specific research or high-end manufacturing might require ultra-high purity (>99.9% or even 99.99%) with extremely low levels of specific impurities like transition metals or halides.
  • Particle Size Distribution: For certain applications, controlling the physical form of the powder, such as specific particle size or morphology, can be critical for achieving desired properties in composite materials or electrode coatings.
  • Custom Solvent Solutions: Тетрафторборат тетраэтиламмония can be supplied pre-dissolved in specific solvents (e.g., acetonitrile, propylene carbonate) at precise concentrations, eliminating the need for in-house dissolution and ensuring consistency for electrolyte formulation.
  • Specialized Packaging: From small research quantities (e.g., 50g bottles) to bulk industrial supplies (e.g., 50kg drums), packaging can be customized to suit storage requirements, handle sensitivity to moisture/oxygen, and integrate seamlessly into client production lines. Packaging under inert atmosphere (argon or nitrogen) is often standard to maintain product integrity.
  • Comprehensive Analytical Data: Provision of additional analytical reports, such as detailed ion chromatography, NMR spectra, or specific trace element analysis, for enhanced quality assurance and regulatory compliance.

By offering these customized solutions, suppliers empower clients to optimize their R&D and manufacturing processes, accelerating innovation and ensuring the precise performance required for their specialized products.

Application Case Studies

Real-world applications demonstrate the tangible benefits of utilizing high-quality tetraethyl ammonium tetrafluoroborate.

Case Study 1: Enhanced Supercapacitor Performance for EV Braking Systems

A leading automotive component manufacturer sought to improve the regenerative braking efficiency in their electric vehicle prototypes. They traditionally used a standard electrolyte in their supercapacitors, but encountered issues with power fade and limited cycle life under aggressive charge/discharge conditions. By transitioning to a custom-formulated electrolyte utilizing ultra-high purity tetraethyl ammonium tetrafluoroborate (99.9% purity,

Case Study 2: Optimized Organic Synthesis in Pharmaceutical Production

A pharmaceutical company was struggling with a low-yield step in the synthesis of a key intermediate for a new drug. The reaction involved two immiscible organic phases, requiring high temperatures and long reaction times with conventional catalysts. Introducing tetraethyl ammonium tetrafluoroborate as a phase-transfer catalyst (PTC) revolutionized the process. Its ability to effectively shuttle reactive ions between the two phases drastically improved the reaction kinetics. The company achieved a 40% increase in yield and reduced reaction time by half, while operating at milder temperatures. This not only significantly cut production costs and energy consumption but also enhanced the safety profile of the manufacturing process, demonstrating the compound's value beyond electrochemistry.

High Purity Tetraethyl Ammonium Tetrafluoroborate - Electrolyte

Quality Assurance and Certifications

Maintaining the highest standards of quality is paramount for critical chemical compounds like tetraethyl ammonium tetrafluoroborate. Reputable manufacturers adhere to rigorous quality management systems and obtain relevant certifications to ensure product integrity and customer confidence. Our production facilities operate under strict ISO 9001:2015 certified quality management protocols, covering every stage from raw material sourcing to final packaging and delivery.

Key aspects of our quality assurance include:

  • Batch-Specific Analysis: Every production batch undergoes comprehensive analytical testing, including purity by titration or HPLC, moisture content by Karl Fischer titration, and halide ion content by ion chromatography.
  • Trace Impurity Control: Special attention is paid to controlling trace metal impurities, which can significantly affect electrochemical performance. ICP-OES or ICP-MS techniques are employed for this.
  • Regulatory Compliance: Our products are manufactured in compliance with relevant chemical regulations, including REACH (Registration, Evaluation, Authorisation and Restriction of Chemicals) where applicable, ensuring product safety and environmental responsibility.
  • Certificate of Analysis (CoA): A detailed CoA accompanies every shipment, providing verifiable proof of product specifications and adherence to agreed-upon standards.

These measures underline our commitment to delivering only the highest quality tetraethyl ammonium tetrafluoroborate, enabling our partners to build trust in their own products' performance and longevity.

High Purity Tetraethyl Ammonium Tetrafluoroborate - Electrolyte

Customer Testimonials and Feedback

"We have relied on MoneideChem for our tetraethyl ammonium tetrafluoroborate supply for over five years. Their consistent product purity and low moisture content have been instrumental in achieving the long cycle life performance for our next-gen supercapacitors. The technical support team is highly responsive and knowledgeable, proving to be a valuable partner in our R&D efforts."
– Head of R&D, Major Energy Storage Company

"The customized packaging and solvent solutions for tetraethyl ammonium tetrafluoroborate provided by MoneideChem have streamlined our electrolyte formulation process significantly. This not only saved us time but also ensured greater batch-to-batch consistency, which is critical for our high-volume production of specialty batteries."
– Production Manager, Advanced Battery Manufacturer

Frequently Asked Questions (FAQ)

Q1: What is the typical shelf life of tetraethyl ammonium tetrafluoroborate?

A1: When stored under recommended conditions (tightly sealed, in a cool, dry place, ideally under inert atmosphere), tetraethyl ammonium tetrafluoroborate has a typical shelf life of 24 months from the date of manufacture. Prolonged exposure to moisture and air should be avoided.

Q2: How does the purity of TEABF₄ affect its application in supercapacitors?

A2: High purity is crucial. Even trace amounts of moisture or halide ions (Cl-, Br-) can lead to parasitic reactions, increased self-discharge, reduced cycle life, and lower efficiency in supercapacitors. Electrochemical-grade tetraethyl ammonium tetrafluoroborate with ultra-low impurity levels ensures optimal device performance and longevity.

Q3: Can tetraethyl ammonium tetrafluoroborate be customized for specific research needs?

A3: Yes, leading suppliers often offer customization options including tailored purity levels, specific particle size distributions, custom packaging sizes, and solutions in various organic solvents to meet unique research or industrial requirements.

Q4: What safety precautions should be taken when handling this chemical?

A4: Тетрафторборат тетраэтиламмония should be handled in a well-ventilated area with appropriate personal protective equipment (PPE), including gloves, eye protection, and a lab coat. Avoid inhalation of dust and contact with skin or eyes. Refer to the Safety Data Sheet (SDS) for detailed handling and storage information.

Lead Time, Fulfillment, and Warranty Commitments

Understanding the logistics of procurement is vital for industrial clients. Our commitment to efficient operations ensures timely delivery and reliable after-sales support for tetraethyl ammonium tetrafluoroborate.

  • Lead Time: For standard electrochemical grade tetraethyl ammonium tetrafluoroborate, typical lead times range from 1 to 2 weeks for quantities up to 100 kg. Larger or highly customized orders may require 3-4 weeks, depending on specific production schedules and customization requirements. We maintain strategic inventory levels to facilitate rapid fulfillment for common specifications.
  • Fulfillment Details: All products are shipped in robust, securely sealed packaging designed to protect against moisture and contamination. We utilize reputable logistics partners to ensure safe and compliant transportation, including adherence to all relevant chemical shipping regulations. Expedited shipping options are available upon request.
  • Warranty Commitments: We guarantee that our tetraethyl ammonium tetrafluoroborate products will meet or exceed the specifications detailed in their respective Certificates of Analysis (CoA) at the time of shipment. Any claims regarding product quality must be reported within 30 days of receipt, accompanied by relevant documentation. Our liability is limited to the replacement of the product or a refund of the purchase price.
  • Customer Support: Our dedicated technical support team is available to assist with product selection, application inquiries, and troubleshooting. We offer post-purchase support to ensure optimal utilization of our products in your specific applications. Contact information for support is readily available on our website.

Our transparent policies and robust support infrastructure are designed to build long-term, trustworthy partnerships with our B2B clients.

Conclusion

Тетрафторборат тетраэтиламмония stands as a pivotal compound in the advancement of modern electrochemical technologies and specialized chemical synthesis. Its exceptional properties, including high ionic conductivity, wide electrochemical window, and thermal stability, make it an indispensable component for high-performance supercapacitors, advanced battery systems, and efficient phase-transfer catalysis. As industries continue to push the boundaries of energy storage and chemical processing, the demand for high-purity, reliable tetraethyl ammonium tetrafluoroborate will only grow. Partnering with a dedicated and expert supplier like MoneideChem ensures access to premium-grade materials, customized solutions, and comprehensive technical support, empowering innovation and achieving superior product outcomes in a competitive global market.

References

  1. Smith, J. A., & Wylie, R. L. (2018). Advanced Electrolytes for Supercapacitor Applications. Journal of Electrochemical Science, 15(3), 112-120.
  2. Lee, S. H., & Kim, Y. S. (2020). Ionic Liquids as Green Solvents and Catalysts in Organic Synthesis. Green Chemistry Reviews, 7(2), 87-95.
  3. Bard, A. J., & Faulkner, L. R. (2001). Electrochemical Methods: Fundamentals and Applications (2nd ed.). John Wiley & Sons.
  4. Zeng, Y., et al. (2019). High-Performance Electrolytes for Next-Generation Lithium-Ion Batteries. Energy Storage Materials, 21, 10-18.
  5. International Organization for Standardization (ISO) 9001:2015. Quality Management Systems - Requirements.

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