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Ferric Ammonium Oxalate | High-Purity Reagent for Cyanotype

  • Time of issue:Oct . 24, 2025 18:15
Tangshan Moneide Trading Co., Ltd. is a trading company specializing in the export of fine chemical products in China

(Summary description)Tangshan Moneide Trading Co., Ltd. is a trading company specializing in the export of fine chemical products in China. Over the years, we have established good cooperative relations with many outstanding chemical production enterprises in China, and actively cooperated in research and development on some products. Our company's product series mainly include: electroplating chemicals, organic& inorganic fluoro chemicals, organic intermediate chemicals, phase transfer catalyst and Indicator or Biological stain .

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  • Time of issue:2019-12-30 10:55
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Information

Ferric ammonium oxalate: what buyers really check before they buy

If you’ve ever mixed chemistry with photography or printmaking, you’ve probably run into Ferric Ammonium Oxalate at some point. Synonyms: ferric ammonium oxalate trihydrate; CAS 13268-42-3. It’s that green, slightly moody complex salt that turns sunlight into images and shop floors into precise etch patterns. The market has been steady, but to be honest, buyers are getting pickier: reproducibility, low heavy metals, and reliable documentation (REACH, RoHS, ISO) now decide who wins the PO.

Ferric Ammonium Oxalate | High-Purity Reagent for Cyanotype

Why it matters in 2025

Three trends: (1) a mini-resurgence of cyanotype and alternative process labs (yes, still going strong); (2) semiconductor-adjacent shops standardizing light-sensitive pre-treatments; and (3) an audit-heavy supply chain where COAs, batch traceability, and ICP-OES heavy metal data are expected, not “nice to have.” Many customers say they’ll accept slightly higher prices if the lot-to-lot curve stays flat.

Typical product specifications

Appearance Green crystals or granules
Assay (as complex, dried basis) ≥ 99.0% (titration vs. KMnO4, ≈ real-world methods may vary)
CAS No. 13268-42-3
Solubility Freely soluble in water (≈100 g/L at 20 °C)
pH (5% aq.) ≈ 2.5–4.0
Moisture (LOD 105 °C) 18–22% (trihydrate indicative)
Fe(II) content ≤ 0.10%
Heavy metals (as Pb) ≤ 10 ppm (ICP-OES)

Process flow (how reputable vendors make it consistent)

Materials: oxalic acid, ferric salt (e.g., FeCl3 or Fe(NO3)3), ammonium source, deionized water. Method: controlled complexation at low pH, filtration, multi-stage washing, crystallization, and low-temperature vacuum drying to protect the hydrate. QC: assay by redox titration, Fe(II)/Fe(III) ratio by UV–Vis, heavy metals by ICP-OES, chloride/nitrate by IC, solution clarity. Testing standards: sampling per ASTM E300; labs often operate to ISO/IEC 17025. Service life: ≈24 months sealed, cool and dry; solutions stay stable ~1–2 weeks refrigerated, away from light. Industries: alternative photography, PCB/etching, lithography pre-treat, academic research, education kits.

Ferric Ammonium Oxalate | High-Purity Reagent for Cyanotype

Application snapshots

  • Cyanotype coating: mix Ferric Ammonium Oxalate with ferricyanide; even crystal size helps smoother coats and less specking.
  • Etching/litho: light-sensitive steps where consistent Fe(III) activity matters for exposure latitude.
  • Analytical reagent: complexometric routines and teaching labs (surprisingly popular again).

Vendor comparison (what buyers ask me for)

Vendor Origin Grades Certs Lead time Notes
Moneide Chemical 2-7-523 Jidong Building Materials, Tangshan, Hebei 064000, China AR, photographic ISO 9001 (on request), REACH support ≈ 2–3 weeks ex-works Strong batch documentation, responsive samples
EU Distributor (generic) EU stock Lab, photo REACH, RoHS statements 1–7 days from stock Higher price, fast delivery
US Specialty Supplier US Photo-grade kits Safety docs, QC sheets 3–10 days Great for small batches, education

Customization and packaging

Options typically include particle size (fine vs. granular to reduce dust), hydration control, and packaging (1 kg amber bottles, 5 kg pails, 25 kg fiber drums with PE liners). Many buyers request tamper-evident seals and light-blocking liners—worth it if you store Ferric Ammonium Oxalate near windows (don’t).

Case notes from the field

A university print studio shifted to tighter-spec Ferric Ammonium Oxalate and reported, informally, fewer “grainy” spots and a ~10–15% reduction in exposure variability. Another customer in PCB prototyping told me switching suppliers cut failures linked to heavy-metal contamination to near zero—small dataset, but encouraging.

Compliance checklist

  • ISO 9001 quality system (verify certificate number and scope).
  • REACH/RoHS statements where applicable.
  • Sampling per ASTM E300; test in ISO/IEC 17025 labs when possible.

Citations

  1. PubChem Compound Summary: Ammonium iron(III) oxalate hydrate. https://pubchem.ncbi.nlm.nih.gov/compound/Ammonium-iron(III)-oxalate-hydrate
  2. ASTM E300 – Standard Practice for Sampling Industrial Chemicals. https://www.astm.org/e0300-20.html
  3. ISO 9001:2015 Quality management systems. https://www.iso.org/standard/62085.html
  4. ECHA – Understanding REACH. https://echa.europa.eu/regulations/reach/understanding-reach
  5. EU RoHS Directive overview. https://environment.ec.europa.eu/topics/waste-and-recycling/rohs-directive_en
  6. Royal Society of Chemistry – Cyanotype resource. https://edu.rsc.org/experiments/cyanotype/1837.article

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